January 24, 2014
his kids carried on his legacy this year
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Since Dalton supposed (incorrectly) that a water molecule consisted of one hydrogen and one oxygen atom, this would imply an atomic weight of oxygen equal to eight. However, expressing the reaction in terms of gas volumes following Gay Lussac’s law of combining gas volumes, two volumes of hydrogen react with one volume of oxygen to produce two volumes of water, suggesting (correctly) that the atomic weight of oxygen is sixteen. The work of Charles Frdric Gerhardt (1816 56), Henri Victor Regnault (1810 78) and Stanislao Cannizzaro (1826 1910) helped to rationalise this and many similar paradoxes, but the problem was still the subject of debate at the Karlsruhe Congress (1860).
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